Total: above the table is the amount spent across every account listed. Each line shows the ACCOUNT and the AMOUNT paid out against it in the period. The row at the foot repeats the total. Accounts with nothing spent in the period do not appear.
The foot row totals the lines on the page you are looking at. A summary by account is usually short enough to fit on one page, so the two totals normally agree. If the report ever runs to a second page, use the Total: above the table.
The printout is headed Shop Paid Outs By Account Category From with your dates, and lists the same accounts and amounts with the total at the foot.
To list the individual payments, with supplier, payment type and description, run Shop Paid Outs Expense Report.